air emissions

Hazardous air pollutants (HAPs), also known as toxic air pollutants or air toxics, are air pollutants that are known or suspected to cause cancer or other serious health impacts. They are associated with elevated cancer levels and other adverse health effects, such as reproductive effects or birth defects. Examples of toxic air pollutants include asbestos, benzene, dioxin, methylene chloride, perchloroethylene, toluene and metals such as cadmium, chromium, lead compounds and mercury.

HAPs can be released to the environment from natural sources, such as volcanic eruptions and forest fires. However, most HAPs originate from human-made sources:

  • Mobile sources: cars, trucks, buses
  • Stationary sources: factories, refineries, power plants
  • Indoor sources: some building materials and cleaning solvents

The U.S. Environmental Protection Agency (EPA) is working with state, local and tribal governments to reduce air emissions of 188 toxic air pollutants to the environment. Any facility emitting air pollutants above certain levels is required to obtain an air permit, which specifies the pollutant limits they must meet so our air quality remains within state and federal standards. State and federal law does not allow the owner/ operator to build or modify a stationary source unless they can demonstrate the project will not cause or contribute to a violation of all applicable state and federal rules, including the National Ambient Air Quality Standards, all of which are developed to be protective of public health.

Screening Model Action Levels

Screening Model Action Levels (SMALs) are emission threshold levels, established by the Missouri Air Pollution Control Program. The main purpose of SMALs is to determine if a site-specific ambient impact analysis should be performed. If the potential emissions of a project exceed these levels, then a site-specific ambient impact analysis is required.

Proposed Screening Model Action Levels

1-Bromopropane

On Jan. 5, 2022, EPA amended the list of hazardous air pollutants under Clean Air Act section 112(b)(1) [Federal Register 87 FR 393], adding 1-bromopropane (Chemical Abstracts Service Number 106–94–5) in response to public petitions previously granted by EPA. The Missouri Department of Natural Resources issued a draft methodology to derive a SMAL to perform air quality analyses specific to 1-bromopropane. The proposed SMAL was available for public comment from Sept. 22, 2023 to Oct. 30, 2023. No public comments were received. The department finalized the new SMAL on Jan. 26, 2024.

2-Methylnaphthalene

The department evaluated the air dispersion modeling of 2-methylnaphthalene (Chemical Abstracts Service Number 91-57-6) required for air construction permits. In response to the evaluation’s findings, the department developed a draft proposal for a new SMAL to perform air quality analyses specific to 2-methylnaphthalene in future air construction permits. The proposed SMAL was available for public comment until May 31, 2023. No comments were received. The department finalized the new SMAL on Jan. 26, 2024.

Risk Assessment Levels

Risk Assessment Levels (RALs) are ambient concentrations of air toxics that are not expected to produce adverse cancer and non-cancer health effects during a defined period of exposure. RALs are based on animal toxicity studies, human clinical studies and human epidemiology studies. They account for exposure to sensitive populations such as the elderly, pregnant women, children and those having respiratory illnesses like asthma. RALs are health-based levels developed, maintained and reviewed by the Missouri Air Pollution Control Program and approved by the Department of Health and Senior Services (DHSS). Similar to the National Ambient Air Quality Standards, if the potential emissions of a project exceeds the RAL, the source must further reduce the ambient impact through permit restrictions or installing controls, until the potential air toxic concentrations are below the RALs. 

Proposed Risk Assessment Levels

Upon request, the department’s Air Pollution Control Program can review a RAL for an individual HAP to ensure consistency with EPA’s guidelines. Revisions to a RAL may take up to eight weeks and will not become effective until approval is received from DHSS. 

1-Bromopropane

On Jan. 5, 2022, EPA amended the list of hazardous air pollutants under Clean Air Act section 112(b)(1) [Federal Register 87 FR 393], adding 1-bromopropane (Chemical Abstracts Service Number 106–94–5) in response to public petitions previously granted by EPA. As a result, the Missouri Department of Natural Resources developed a draft proposal for new 24-hour and annual RAL to perform air quality analyses specific to 1-bromopropane in future air construction permits. The proposed RAL was available for public comment from May 1, 2023 to May 31, 2023. No public comments were received. The department finalized the new RAL on Jan. 26, 2024.  

Lead and Lead Compounds

In July 2023, Ramboll submitted a whitepaper to the Missouri Department of Natural Resources, requesting a review of the risk assessment levels for lead and lead compounds (Chemical Abstracts Service Number 7439–92–1). After reviewing the whitepaper and EPA’s Integrated Science Assessment for Lead, External Review Draft, the department found it appropriate to use the National Ambient Air Quality Standard (NAAQS) for lead as the new RAL. The Missouri Department of Health and Senior Services agreed with the department’s proposal on Oct. 26, 2023. The proposal was available for public comment from Nov. 27, 2023 to Dec. 27, 2023. No public comments were received. The department finalized the new RAL on Jan. 26, 2024.